Long-context LLM inference is bottlenecked not by compute but by the O(n) memory bandwidth cost of scanning the KV cache at every decode step -- a wall that no amount of arithmetic scaling can break. Recent photonic accelerators have demonstrated impressive throughput for dense attention computation; however, these approaches inherit the same O(n) memory scaling as electronic attention when applied to long contexts. We observe that the real leverage point is the coarse block-selection step: a memory-bound similarity search that determines which KV blocks to fetch. We identify, for the first time, that this task is structurally matched to the photonic broadcast-and-weight paradigm -- the query fans out to all candidates via passive splitting, signatures are quasi-static (matching electro-optic MRR programming), and only rank order matters (relaxing precision to 4-6 bits). Crucially, the photonic advantage grows with context length: as N increases, the electronic scan cost rises linearly while the photonic evaluation remains O(1). We instantiate this insight in PRISM (Photonic Ranking via Inner-product Similarity with Microring weights), a thin-film lithium niobate (TFLN) similarity engine. Hardware-impaired needle-in-a-haystack evaluation on Qwen2.5-7B confirms 100% accuracy from 4K through 64K tokens at k=32, with 16x traffic reduction at 64K context. PRISM achieves a four-order-of-magnitude energy advantage over GPU baselines at practical context lengths (n >= 4K).